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Ninth-seeded former Wimbledon runner-up Marion Bartoli handled fellow Frenchwoman Virginie Razzano 7-5, 6-0, while German Sabine Lisicki, the 14th seed, advanced with a 6-2, 4-6, 6-4 win against Swiss Stefanie Voegele and 15th-seeded capable Russian Anastasia Pavlyuchenkova bested Czech Klara Zakopalova 7-6 (7-5), 6-1.
Several other women reached the round of 64, including Israeli Shahar Peer, Americans Vania King and Sloane Stephens, Canadian Aleksandra Wozniak, Chinese Zheng Jie, and Aussie favorite Jelena Dokic, who drubbed Russian and fellow former top-10 star Anna Chakvetadze 6-2, 6-1. Zheng drilled American Madison Keys 6-2, 6-1, while King defeated Ukrainian Kateryna Bondarenko 7-6 (7-3), 6-3 and Stephens stopped Spaniard Silvia Soler-Espinosa 6-4, 6-2.
The second round will get underway on Wednesday, including matches for world No. 1 Caroline Wozniacki, third-seeded Victoria Azarenka, fifth-seeded 2011 Aussie Open runner-up and French Open champion Li Na and 11th-seeded reigning Melbourne titlist Kim Clijsters.
Clijsters beat Li in last year's Aussie finale.
The 24-year-old Djokovic lost two of the first three games to Italy's Paolo Lorenzi, then won a whopping 17 in a row to finish off a commanding 6-2, 6-0, 6-0 win at the season's first Grand Slam event.
The three-time Grand Slam finalist Murray has been the Melbourne runner-up the last two years. He'll meet Frenchman Edouard Roger-Vasselin on Thursday.
And American Andy Roddick, a four-time Aussie semifinalist who is seeded 15th at this particular fortnight, had little trouble in a 6-3, 6-4, 6-1 win over Dutchman Robin Haase.
Battling the heat, Djokovic popped four aces among his 22 winners against Lorenzi, who committed 30 unforced errors and won just 56 percent of his first serves at Melbourne Park.
Still, Djokovic bounced back to win Wimbledon and the U.S. Open and owns four career Grand Slam titles, including his first Aussie championship back in 2008.
He is trying to become only the fourth player on the men's side to win three or more Australian Open titles in the Open era (since 1968).
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